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A given volume of methane diffuses in 20 second... - WAEC Chemistry 1997 Question

A given volume of methane diffuses in 20 seconds. How long will it take the same volume of sulphur (IV) oxide to diffuse under the same conditions? [CH4 = 16; SO2 = 64]

A
5 seconds
B
20 seconds
C
40 seconds
D
60 seconds
correct option: c

Applying the Graham's law defination; i.e,

\(\frac{R(SO_2)}{R(CH_4)} = \sqrt{\frac{M(CH_4)}{M(SO_2)}} = \frac{t(CH_4)}{t(SO_2)}\)

Where t(SO\(_2\)) = ?, M(SO\(_2\)) = 64

t(Ch\(_4\)) = 20 sec, M(Ch\(_4\)) = 16

therefore, \(\frac{t(SO_2)}{20}\) = \(\sqrt{\frac{64}{16}}\)

\(\frac{t(SO_2)}{20}\) = \(\frac{8}{4}\)

t(SO\(_2\)) = 8 x \(\frac{20}{4}\)

= 40 sec.

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